Durable, bio-based fibers
Revealing the potential of hemp-based textile materials
University College Ghent, Ghent/Belgium
Physical properties of hemp tissues – a comparison with cotton
The tested fabrics are:
• Hemp tissue: bleached; undyed; plain weave; 207 g/m2 (Libeco Lagae, Meulebeke/Belgium)
• Hemp tissue: dyed (green); plain weave; 147 g/m2 (Ecological Textiles, Roermond/Netherlands)
• Hemp/organic cotton tissue 55/45: dyed (blue); twill; 324 g/m2 (Ecological Textiles)
• Hemp/polyester tissue 55/45: bleached; undyed; twill; 278 g/m2 (Ecological Textiles)
• Cotton tissue: bleached; undyed; Panama bond; 250 g/m2 (Concordia Textiles NV, Waregem/Belgium)
Determination of the essential, physical characteristics of the mentioned tissue types is done based on the test matrix presented in Table 1.
The main observations (Table 2) are:
• Hemp tissues can offer essential, mechanical properties within market-proof margins for casual and workwear.
• The tested 100 % hemp tissues show limitations with regard to abrasion resistance, pilling tendency and susceptibility to crease formation.
• The drawbacks of pure hemp can be (partially) overcome by means of application of intimate yarn mixtures e.g. hemp/organic cotton or hemp/recycled polyester.
• Only in the case of the low weight, green hemp tissue has an acceptable seam slippage limit value of 3 mm (cf. jeans) been exceeded.
• Concerning dimensional stability during industrial washing at 60 °C, hold maximal deformation limits are normally within ± 2 %. None of the tested substrates reach this level in both directions (warp, weft).
Impact of liquid ammonia treatment on cellulosics
Liquid ammonia treatment can be done under subcontracting at Veramtex S.A., Brussels/Belgium (B – Beau-Fixe process). The treatment scheme is presented in Fig. 1. Step A stands for the substrate dipping into liquid ammonia (-33 °C) at atmospheric pressure during less than 10 seconds. Steps B and C intend the complete ammonia removal afterwards over heat treatment (120 °C) respectively rinsing in water (80 °C). The last step (D) is formed by substrate drying on a stenter system. More than 99 % of the applied ammonia is finally recovered by means of adequate distillation. The Beau-Fixe treatment is Standard 100 and STeP by Oeko-Tex certified.
The impact of ammonia treatment onto cellulosic fibers (CO, CV, L) is highly comparable with mercerization. The individual cotton fibers lose their typical torsions (up to 60 torsions/cm) while heavily swelling. Crystalline and semi-crystalline zones become permanently modified by this. A stabilized material is finally formed. A distinctive example is given in Fig. 2.
© Foto: de Raeve
Fig. 2 Positive impact of Beau-Fixe treatment onto shape retention during washing
This study aims to give a practical insight in the transferability of the Beau-Fixe treatment from cellulosic materials like cotton and flax to hemp. The earlier mentioned physical test protocol (Table 1) has been worked out on the bleached cotton and hemp tissue selection. Results are summarized in Table 3.
© Foto: De raeve
In case of the bleached cotton tissue a significant upgrade of physical properties is attained after ammonia finishing: a) tensile strength in warp direction: +13.8 %; b) abrasion resistance: 15,000 turns 35,000 turns; c) less crease susceptibility; d) deformation after industrial washing ≤ 2 %. Seam slippage values heighten (read: lower yarn slip resistance compared to rounder fiber cross-section), but are still below 3 mm (see ECLA guidelines). FTT analysis reveals a completely similar haptic aspect before and after ammonia processing of the bleached cotton tissue.
The effect of liquid ammonia finishing on the dyeability behavior is evaluated. All performed dyeing processes obtain a higher dyeing yield under the condition of NH3 pretreatment: rising color depths are indicated by higher K/S and lower L values. Each time a visible color difference for the human eye (i.e. delta E > 1) is observed. Rubbing (dry/wet bleeding) and washing (bleeding vs. degradation) fastness levels are determined over normalized tests: ISO 105-X12 respectively ISO 105-C06: C1M (60 °C). Out of this it can be concluded that ammonia pretreatment does not influence the fastness properties of the dyed materials.
The basic hydrophilic character of bleached and/or dyed cotton and hemp tissue types is determined by means of a Moisture Management Testing system. The evaluated hemp tissues in pure and mixed form show a similar and good interaction with water (minimal degree of 3.05), comparable to that of equivalent, cotton tissues.
© Foto: De raeve
© Foto: de raeve
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